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  • 标题:SYNTHESIS, ACTIVITY AND THERMAL STABILITY OF GOLD NANOPARTICLE ON MODIFIED NH4-Y TYPE ZEOLITE FOR COOXIDATION
  • 本地全文:下载
  • 作者:ASILIAN MAHABADI HASAN ; JAFARI S. ; KHAVANIN A.
  • 期刊名称:IRANIAN JOURNAL OF ENVIRONMENTAL HEALTH SCIENCE AND ENGINEERING (IJEHSE)
  • 印刷版ISSN:1735-1979
  • 出版年度:2007
  • 卷号:4
  • 期号:4
  • 页码:263-269
  • 语种:English
  • 出版社:IRANIAN ASSOCIATION OF ENVIRONMENT HEALTH, TEHRAN, UNIVERSITY OF MEDICAL SCIENCES
  • 摘要:

    Gold nanoparticle is the active catalyst for CO oxidation at low temperature. This feature of gold base catalysts is suitable to overcome the problem of cold-start problem of automobile exhaust TWC converters. In this study gold nanoparticle were deposited on modified NH4-Y type zeolite. The activity of synthesized catalyst was measured in a fixed-bed quartz-tubular reactor (7mm i.d.) under atmospheric pressure. In order to investigate the catalytic activities toward CO oxidation reaction, 31mL/min of air and 0.155mL/min of carbon monoxide were mixed and then passed through the reactor. It was found that activity of Au/Y catalyst was 100% at 20 ° C. The thermal stability of Au/Y catalyst was measured at 400 ° C for 4h. The activity of the catalyst was decreased to 65% at 20 ° C after thermal stability test. Results of Energy Dispersive Analysis by X-rays before and after thermal stability have showed that Au content of these samples were 3.89% and 1.76, respectively. It was found that the amount of Au content decreased after thermal stability process. Fourier Transform Infrared (FT-IR) spectra showed no changes in framework structure of zeolite during thermal stabilization process of the catalyst.

  • 关键词:GOLD NANOPARTICLE; NH4Y-TYPE ZEOLITE; CO OXIDATION; CATALYST; THERMAL STABILIZATION
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