期刊名称：Iranica Journal of Energy and Environment (IJEE)
印刷版ISSN：2079-2115
电子版ISSN：2079-2123
出版年度：2012
期号：3143
页码：143-156
出版社：Noshirvani University of TEchnology
摘要：The present study deals with the application of Watermelon Shell, an agricultural waste, for the adsorptive removal of Cu(II) from its aqueous solutions. This paper incorporates the effects of time, dose,temperature, concentration, particle size, agitation speed and pH. Analytical techniques have been employed to find pore properties and characteristics of adsorbent materials. Batch kinetic and isotherm studies have also been performed to understand the ability of the adsorbents. The adsorption behavior of the Cu(II) has beenstudied using Freundlich, Langmuir and Tempkin adsorption isotherm models. The monolayer adsorption capacity determined from the Langmuir adsorption equation has been found as 111.1 mg/g. Kineticmeasurements suggest the involvement of pseudo-second-order kinetics in adsorptions and is controlled by a particle diffusion process. Adsorption of Cu(II) on adsorbents was found to increase on decreasing initial concentration, increasing pH up to 8, increasing temperature, increasing agitation speed and decreasing particlesize. Overall, the present findings suggest that watermelon outer shell is environmentally friendly, efficient and low-cost biosorbent which is useful for the removal of Cu(II) from aqueous media.
