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  • 标题:Electrochemical and thermodynamical investigation of Schiff’s bases of Glycine and Aldehydes on Corrosion inhibition behavior of Mild steel in 1M hydrochloric acid medium
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  • 作者:khandelwal L. ; Verma C.B. ; Quraishi M.A.
  • 期刊名称:Journal of Materials and Environmental Science
  • 印刷版ISSN:2028-2508
  • 出版年度:2015
  • 卷号:6
  • 期号:3
  • 页码:810-817
  • 出版社:University of Mohammed Premier Oujda
  • 摘要:Three Schiff's bases (SBs) namely 2-(2-hydroxybenzylidene amino) acetic acid (HBAA), 2-(4-(dimethylamino) benzylidene amino) acetic acid (DMBA), and 2-(2-hydroxy-4-methyxybenzylidene amino) acetic acid (HMBA) were synthesized and their effects on the electrochemical behavior of mild steel in 1 M HCl was investigated using gravimetric measurements, Tafel extrapolation technique, linear polarization resistance (LPR) and electrochemical impedance spectroscopy (EIS) methods. Tafel polarization measurements revealed that these Schiff's bases act as mixed-type inhibitors. Among the studied SBs, HMBA exhibited the best inhibition efficiency of 95% at 400 ppm concentration. Some thermodynamic parameters were also determined to investigate the mechanism of adsorption. The results obtained from weight loss and electrochemical methods are in good agreement
  • 关键词:Acid corrosion; Mild steel; Thermodynamic parameter; EIS
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