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  • 标题:Pyrolysis Biochar from Cellulosic Municipal Solid Waste as Adsorbent for Azo Dye Removal: Equilibrium Isotherms and Kinetics Analysis
  • 本地全文:下载
  • 作者:Manu Agarwal ; James Tardio ; S. Venkata Mohan
  • 期刊名称:International Journal of Environmental Science and Development
  • 印刷版ISSN:2010-0264
  • 出版年度:2015
  • 卷号:6
  • 期号:1
  • 页码:67-72
  • DOI:10.7763/IJESD.2015.V6.563
  • 摘要:AbstractMunicipal solid waste (MSW) can have a negative impact on the environment and / or human health, if not properly managed. Though landfill is the most common method used to manage MSW, treating MSW using waste-toenergy (WtE) technologies is an option that is receiving increasing interest. Pyrolysis is a WtE technology that is capable of converting waste into products such as bio-gas, biooil and bio-char. Bio-char, which varies in composition based on the raw material pyrolysed, has the potential to be used as a fuel and as an applied material for catalysis or adsorption. In this work the removal of azo dye was investigated using biochar from pyrolysis of a cellulosic municipal solid waste. The bio-char was characterised using Scanning Electron Microscopy and Surface Area Analysis. The influence of pH on the dye removal was investigated over the range 4-7. The experimental data was analysed using four non-linear kinetic models (Pseudo first-order, pseudo second-order, Weber intraparticle diffusion and Elovich equation) and four non-linear isotherm models (Langmuir, Freundlich, Temkin and Sips), and ranked based on the statistical analysis tools in origin software. The dye removal kinetics most closely followed pseudo-first order kinetics whilst the adsorption isotherms were most closely fitted by the Temkin model over the pH range studied.
  • 关键词:Azo dye; bio; char; municipal solid waste; water treatment
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