The emerging technology enterprises are the important supporter that emerging technology evolves into emerging industry, emerging technology enterprises entrepreneurial ability promotion path is a very complex fuzzy concept, how to improve entrepreneurial ability and this article defines that entrepreneurial ability has become a problem for emerging technology enterprises to keep their competitive advantage to be solved, this article has built research framework and structural equation model based on the theoretical analysis and selected 492 emerging technology enterprises as research objects. It quantitatively discusses the influence which market orientation, entrepreneurial learning and innovative way have on entrepreneurship. According to the result, to modify the model, come to the conclusion that China's emerging technology enterprise business ability and experience, the path of ascension is beneficial to provide reference for the same type enterprises in our country for reference, which will improve the development of emerging industry.