期刊名称：Studia Universitatis Moldaviae: Stiinte Sociale
印刷版ISSN：1814-3199
电子版ISSN：2345-1017
出版年度：2014
卷号：1
期号：71
页码：135-141
出版社：Moldova State University
摘要：A fost realizat. sinteza unei serii de dioxima.i ai cobaltului(III), .n care, .n afar. de liganzii dioximici (metilglioxima – MH 2 , dimetilglioxima – DH 2 , difenilglioxima – DfH 2 , 1,2-ciclohexandiondioxima – NioxH 2 ) la atomul central coordi- neaz. diferi.i liganzi organici (tiocarbamida, piridina, anilina, nicotinamida, sulfanilamida, orto-fenantrolina). .n depen- den.. de natura liganzilor axiali, are loc aranjarea spa.ial. specific. a mo leculelor asamblate. Sarcina cationului complex este compensat. de anionul tetrafluoroborat, care .mpreun. cu moleculele de ap. formeaz. un sistem de leg.turi de hidrogen. Unii reprezentan. i ai acestei serii manifest. propriet..i biostimulatoare .n procesele de enzimogenez. la unele tulpini de fungi
其他摘要：The synthesis of a serie of cobalt(III) dioximates (methylglyoxime – MH 2 , dimethylglyoxime – DH 2 , diphenil- glyoxime – DfH 2 , 1,2-ciclohexanedionedioxime – NioxH 2 ) has been performed, which have some additional organic ligands (thiocarbamide, pyridine, aniline, nicotinamide, sulfanilamide, ortho-phenanthroline) coordinated to the central atom. It was proved that the specific spatial arrangement of the assembled molecules depends on the nature of the axial ligands. The charge of the cationic complex is compensated by the tetrafluoroborate anion, which forms a system of hydrogen bonds with the water molecules. Several representatives of this series are good biostimulators of enzymogenes processes of some fungal strains
