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  • 标题:Catecholase and tyrosinase biomimetic activities for heteroatom donor ligands: Influence of five parameters
  • 本地全文:下载
  • 作者:Mouadili A. ; El Ouafi A. ; Attayibat A.
  • 期刊名称:Journal of Materials and Environmental Science
  • 印刷版ISSN:2028-2508
  • 出版年度:2015
  • 卷号:6
  • 期号:8
  • 页码:2166-2173
  • 出版社:University of Mohammed Premier Oujda
  • 摘要:The in-situ transition metal complexes of five ligands L 1 -L 5 were reported and examined for their catecholase activities at ambient conditions, we found that reaction rate depends on five parameters: Nature of the ligand; nature of metal salts, concentration of the combination of metal/ligand; nature of solvent and nature of the substrate. The highest rate activity is given by the in-situ complex formed by ligand L 1 and metal salt Cu(CH 3 CO 2 ) 2 which is equal to 19.04 μmol.L -1 min -1 .
  • 关键词:pyrazol; catechol; heteroatom compound; transition metal; oxidation reaction
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