标题:The micelle formation of cationic and anionic surfactants in aqueous medium: Determination of CMC and thermodynamic parameters at different temperatures
期刊名称:Journal of Materials and Environmental Science
印刷版ISSN:2028-2508
出版年度:2015
卷号:6
期号:10
页码:2711-2716
出版社:University of Mohammed Premier Oujda
摘要:In this paper, the micellization of anionic surfactant sodium dodecyl sulphate (SDS) and cationic surfactant N - dodecylpyridinium chloride (D PC) in aqueous solution at various temperatures has been reported using conductivity measurements. The thermodynamic parameters of micellization ; the free energy, 0 mic Δ G , the enthalpy, 0 mic Δ H , and the entropy, 0 mic Δ S were calculated from the critical micelle concentration (CMC) at different temperatures. T he results show that the CMC of surfactants decreases to reach a minimum and then increases with temperature. Also, the thermodynamic parameters of micellization are discussed