期刊名称：International Journal of Innovative Research in Science, Engineering and Technology
印刷版ISSN：2347-6710
电子版ISSN：2319-8753
出版年度：2015
卷号：4
期号：1
页码：18681
DOI：10.15680/IJIRSET.2015.0401046
出版社：S&S Publications
摘要：A series of 20CaO-10ZnO-59.9P2O5-10Pb3O4-0.1x, (x= V2O5, Cr2O3, MnO and CuO) glasses wasprepared by melt quench technique. Spectroscopic properties of the prepared glass systems were investigated using XRaydiffraction, Ultra-Violet (UV) spectroscopy, Differential Scanning Calorimetry (DSC), Electron ParamagneticResonance (EPR – X band), Fourier Transform Infra Red (FTIR) spectroscopy and Raman spectroscopy. Presentinvestigation is useful to study the effect of glass composition on the optical, thermal, physical properties andsymmetry of the prepared glasses. Various physical properties for all the glasses were measured. X-ray diffraction ofglass samples was carried to check its amorphous nature. From EPR spectra, the spin-Hamiltonian parameters werecalculated and these parameters were influenced by the change in glass composition for different transition metal ions.The FTIR spectral investigations of glasses revealed characteristic vibrations of PO43- units. The Raman spectra of allglass samples have displayed different spectral bands, and intensity of these bands. The results showed that the networkstructure of these glass samples is found to be change from glass to glass.
