期刊名称：International Journal of Innovative Research in Science, Engineering and Technology
印刷版ISSN：2347-6710
电子版ISSN：2319-8753
出版年度：2015
卷号：4
期号：3
页码：1032
DOI：10.15680/IJIRSET.2015.0403044
出版社：S&S Publications
摘要：Lead zinc phosphate glasses containing 0.1% transition metal ion Cr3+ were prepared by melt quenchingtechnique and their amorphous nature confirmed by X-Ray diffraction. The covalent bond nature of Cr3+ ions withoctahedral symmetry in glass network was established through Electron Paramagnetic Resonance and opticalabsorption spectroscopic studies. Endothermic dip for glass transition temperature (Tg) at about 410 0C and anexothermic peak subsisted from thermal studies were obtained. De-polymerization of host glass network due toaddition of alkali content to the glass matrix, has turned as a strong candidate for nonlinear optical laser applications.
关键词：Amorphous materials; Electron Paramagnetic Resonance; Optical spectroscopy; Lead Zinc Phosphate;glass; Ligand field theory.
