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  • 标题:ZSM5 as a Potential Catalyst for Glycerol Pyrolysis
  • 本地全文:下载
  • 作者:Margarida L. Castelló ; Jo Dweck ; Donato A. G. Aranda
  • 期刊名称:Journal of Sustainable Bioenergy Systems
  • 印刷版ISSN:2165-400X
  • 电子版ISSN:2165-4018
  • 出版年度:2014
  • 卷号:04
  • 期号:01
  • 页码:61-67
  • DOI:10.4236/jsbs.2014.41006
  • 语种:English
  • 出版社:Scientific Research Publishing
  • 摘要:Glycerol is a substance known to humankind for many years now, and among other products, in which composition it is used, are the pharmaceutical, cosmetic, food, paints and varnishes REF _Ref382993082 \r \h [1]REF _Ref382993086 \r \h [6]. The abundance of its supply leads to search for new uses, whether as a plasticizer for biodegradable polymers REF _Ref382993096 \r \h [7], its transformation into other substances like propylene and derivatives or other hydrocarbons [8] [9], the production of hydrogen for energy purposes REF _Ref382993109 \r \h [10], or even direct burning, making glycerol a fuel for boilers, for example. The aim of this work was to investigate the action of the zeolite ZSM5 on glycerol fast pyrolysis at 600°C. The tests were done with a mixture of glycerol-ZSM5 recently prepared using approximately equal volumes of glycerol and the catalyst, and the effluent gases from the fast pyrolysis have been analyzed in a chromatography/mass spectrometry (GC/MS) system. Experiments showed that ZSM5 acts in the pyrolysis of glycerol leading to a large number of substances, from oxygenated products to hydrocarbons, which are part of typical compositions of naphtha, diesel and gasoline petroleum derived products.
  • 关键词:Glycerol; ZSM5; Pyrolysis
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