期刊名称：International Journal of Innovative Research in Science, Engineering and Technology
印刷版ISSN：2347-6710
电子版ISSN：2319-8753
出版年度：2015
期号：NCAC
页码：67
出版社：S&S Publications
摘要：A systematic kinetic study on the oxidation of histidine by peroxomonosulphate (PMS) in acetic acidsodiumacetate buffered medium (pH 3.6-4.8) and the catalytic effect of copper(II) was investigated. EPR spectral dataruled out the involvement of free radical intermediate. Formation of copper – histidine – PMS complex was establishedby cyclic voltammetric and UV –visible absorption studies. NMR studies confirmed that the product formed in thisreaction was imidazole -4-acetaldehyde. A suitable mechanism was proposed.
