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  • 标题:Equilibrium Based Computer Studies of Heterobinuclear Complexes of Toxic Metal Ions Involving Biologically Significant Ligands
  • 本地全文:下载
  • 作者:K. Kumar ; D. K. Dwivedi
  • 期刊名称:International Journal of Innovative Research in Science, Engineering and Technology
  • 印刷版ISSN:2347-6710
  • 电子版ISSN:2319-8753
  • 出版年度:2014
  • 卷号:3
  • 期号:7
  • 页码:14711
  • 出版社:S&S Publications
  • 摘要:The chemical equilibria of multinuclear complexation of toxic metal ions Cd (II) and Pb (II) with 2-Amino-3-(4-hydroxyphenyl) propanoic acid and 2, 4-dihydroxypyrimidine ligands in aqueous solution were studied bypotentiometric technique. The metal ligand formation constants of investigated binary, ternary and quaternary metalchelates were determined at 3710C and fixed ionic strength I =0.1M NaNO3 by using SCOGS and the complexformations were studied on the basis of computer analysis. Solution structure and stability order of studied binary(MA, MB) ternary (MAB) and quaternary (M1M2AB) complexes have been discussed.
  • 关键词:Formation Constant; SCOGS; Distribution Curves; Complexes; Stability Order
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