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  • 标题:Oxidation Kinetics of D-Ribose by µ- Peroxo Complex in Aqueous Medium
  • 本地全文:下载
  • 作者:S. Ignatius Arockiam ; A. Peter Pascal Regis
  • 期刊名称:International Journal of Innovative Research in Science, Engineering and Technology
  • 印刷版ISSN:2347-6710
  • 电子版ISSN:2319-8753
  • 出版年度:2014
  • 卷号:3
  • 期号:9
  • 页码:15931
  • DOI:10.15680/IJIRSET.2014.0309020
  • 出版社:S&S Publications
  • 摘要:A solution route method was carried out for the synthesize of μ-peroxo-bis [aminebis (ethylenediamine)cobalt(III) ]perchlorate dihydrate. FT-IR and Electronic spectroscopic methods were used to characterize the synthesizedcomplex. Biomimic oxidation of D-ribose by μ-peroxo complex has been studied kinetically in aqueous medium. Pseudofirst order conditions has been followed to determine the rate of the reaction. The Oxidation reaction shows first orderkinetics with respect to peroxo complex concentration and hydrogen ion concentration. The reaction rate points tonegligible effect on increasing ionic strength. Potentiometric method was used to carry out the biomimic oxidation of thecomplex μ-peroxo complex. Thermodynamic and Arrhenius parameters were calculated and a plausible mechanism hasbeen proposed.
  • 关键词:Kinetics; Oxidation; peroxo complex; D-ribose; Activation parameters
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