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  • 标题:Synthesis and Characterization of Si (IV) Complexes with Salen-Type Ligand
  • 本地全文:下载
  • 作者:Gurjaspreet Singh
  • 期刊名称:International Journal of Innovative Research in Science, Engineering and Technology
  • 印刷版ISSN:2347-6710
  • 电子版ISSN:2319-8753
  • 出版年度:2014
  • 卷号:3
  • 期号:9
  • 页码:15940
  • DOI:10.15680/IJIRSET.2014.0309022
  • 出版社:S&S Publications
  • 摘要:The silicon(IV) compounds possessing SiN4O2 (1), SiN2O2C2 (2,4) and SiN2O2CCl (3) coordinatingframeworks have been synthesized in high yield by the reaction of the O,N,N,O- donor salen-type ligand L withdifferent silanes i.e. diethoxydiisocyanatosilane (C2H5O)2Si(NCO)2, dichlorodiphenylsilane (Ph2SiCl2),trichlorophenylsilane (PhSiCl3) and dichloromethylphenylsilane (MePhSiCl2). The compounds 1-4 have beencharacterized by elemental analysis, IR, 1H NMR and 13C NMR spectroscopy.
  • 关键词:Schiff base; Silane; Silicon (IV) compound.
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