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  • 标题:Chemical characterization using the infrared spectra to remove sulfur element from thiourea compound as a one of the organic compounds present in crude oil using a modern method: Metal ions plays the role of catalyst
  • 本地全文:下载
  • 作者:Mousa A.A. Al-Yazedy ; Samy M. El-megharbel ; Moamen S. Refat
  • 期刊名称:International Journal of Innovative Research in Science, Engineering and Technology
  • 印刷版ISSN:2347-6710
  • 电子版ISSN:2319-8753
  • 出版年度:2013
  • 卷号:2
  • 期号:12
  • 页码:7121
  • 出版社:S&S Publications
  • 摘要:Manganese, zinc and cadmium(II) thiocyanate, M(SCN)2.xH2O, is obtained by a new synthetic methodinvolving the reaction of aqueous solutions of MnCl2, Zn(NO3)2.6H2O and CdCl2 with thiourea at ~ 90oC. The infraredspectrum of the formed product clearly indicates the absence of bands due to thiourea and shows the characteristic bands ofthiocyanate ion. A general mechanism describing the formation of metal thiocyanate, M(SCN)2.xH2O, is suggested.
  • 关键词:thiocyanate SCN–; infrared spectra; transition metals; thiourea.
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