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  • 标题:New chemical procedures for preparation of manganese(II), cobalt(II), zinc(II) and cadmium(II) carbonates under the catalytic behavior of metal ions: Discussion of infrared spectral bands
  • 本地全文:下载
  • 作者:Samy M. El-Megharbel ; Ahmed El-Maghraby ; Moamen S. Refat
  • 期刊名称:International Journal of Innovative Research in Science, Engineering and Technology
  • 印刷版ISSN:2347-6710
  • 电子版ISSN:2319-8753
  • 出版年度:2013
  • 卷号:2
  • 期号:12
  • 页码:7448
  • 出版社:S&S Publications
  • 摘要:Mn(II), Co(II), Zn(II) and Cd(II) carbonates, respectively, were achieved by a new chemical procedure underthe reaction of aqueous solutions of metal ions (MnCl2, Co(NO3)2, Zn(NO3)2 or CdCl2), potassium iodide and urea withmolar ratio 1:2:10, respectively, at ~ 90 oC for 3 hrs. The infrared spectra of the results indicate absence of the essentialbands of urea, but existed of the characteristic bands of ionic carbonate, CO32–. An important chemical mechanismsdiscussed the preparation of Mn(II), Co(II), Zn(II) and Cd(II) carbonate compounds were suggested.
  • 关键词:carbonate CO3;2–; infrared spectra; transition metals; potassium iodide; urea
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