期刊名称:Majalah Iptek = IPTEK : The Journal for Technology and Science
印刷版ISSN:0853-4098
电子版ISSN:2088-2033
出版年度:2008
卷号:19
期号:3
DOI:10.12962/j20882033.v19i3.147
语种:English
出版社:IPTEK
摘要:In this work, mixing rule of Sanches-Lacombe equation of state (SL-EoS) was developed for estimating vapor-liquid equilibria of solvent-polymer systems or solubility of solvent in polymer solutions. The model was derived by matching excess Gibbs energy of Sanches-Lacombe equation of state and that of group contribution model at zero pressure. Present model can be applied to wide range of pressure. In addition, this model covers systems with various molecular interactions, since functional group interaction parameters of UNIFAC-FV and UNIFAC-ZM models have been available for various groups.
关键词:Equation of State; Mixing Rule; Solubility; Polymer and Solvent