期刊名称：Studia Universitatis Moldaviae: Stiinte Sociale
印刷版ISSN：1814-3199
电子版ISSN：2345-1017
出版年度：2009
卷号：1
期号：21
页码：152-156
出版社：Moldova State University
摘要：It has been carried out the oriented synthesis of the new Co(III) dioxymates with complex anions of . uorine of type [Co(DioxH) 2 L 2 ] n X.mH 2 O, where DioxH - is the radical of dioxime: dimethylglyoxime (DH 2 ), 1,2-ciclohexandionedioxi- me (NioxH 2 ); L – aniline (An), thiocarbamide (Thio), pyridine (Py); X – [SbF 6 ] - , [TiF 6 ] 2- . The Cо(III) trans-dioximates form octahedric compounds with pseudomacrocyclic basis and neutral anionic ligand on the apical coordinates. The formation of the crystal structures is primarily governed by outer-sphere anions [TiF 6 ] 2– , [SbF 6 ] - and crystallization water molecules
