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  • 标题:Thermodynamic and Analytical Study at infinite dilution of Non- polar organics solution by IGC used Schiff Base Liquid crystal as stationary phase
  • 本地全文:下载
  • 作者:Boudaoud A. ; Djedid M. ; Benalia M.
  • 期刊名称:Journal of Materials and Environmental Science
  • 印刷版ISSN:2028-2508
  • 出版年度:2016
  • 卷号:7
  • 期号:6
  • 页码:1979-1987
  • 出版社:University of Mohammed Premier Oujda
  • 摘要:This article describes the thermodynamic parameters and phase behaviour of a Schiff Base Liquid crystal , the mesogene was synthesized in the five chemical reactions and characterized by FTIR , 1H and 13C - NMR techniques. The mesomorphic properties were studied using di fferential scanning calorimetry (DSC) and polarizing optical microscopy (POM) , T he retention diagrams of n - alkanes on the sta tionary phase were plotted at temperatures in °C between 100 and 170 by inverse gas chromatography technique. T he separation of n - alkanes was estimated using retention times in the infinite dilution region. T he t hermodynamic parameters of intermolecular in teractions between the stationary phase and n - alkanes (free energy, enthalpy, and entropy ) were calculated and the results were discussed.
  • 关键词:Stationary Phase; Schiff Base; IGC; n;Alkanes; Thermodynamic Parameters; Liquid crystals
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