期刊名称：Journal of Materials and Environmental Science
印刷版ISSN：2028-2508
出版年度：2016
卷号：7
期号：6
页码：2042-2050
出版社：University of Mohammed Premier Oujda
摘要：The synthesisvia the Cu(I)-catalyzed Huisgen dipolar cycloaddition of N,N.-Bis(triazolyl) N,N-dimethyl- propyldiamineL 2 , from commercial N,N'-dimethyl-propyldiamine. This ligand bears two propanol moieties connected to triazoles via the azote for increasing water solubility and overcome the dissolution problems encountered in the previous works. The interaction of these ligands with NiII, CuII, and ZnII cations were fully investigated by UV/Vis and 1 H and 13 C NMR, cyclic voltammetry and electron paramagnetic resonance (EPR) spectroscopies. The copper(II) complex have a square-based pyramidal geometry, as witnessed by the reported spectroscopic, UV/Vis and EPR features. The stoichiometry of the complexes was established from the elemental analysis, Mass and UV-visible spectroscopies.
关键词：N;N;diamine; [1;2;3]Triazole; Cu ; II ; complexes; Cyclic voltammetry
