标题:A new route for the synthesis of symmetric and dissymmetric bis-triazol ligands and the catechol oxidase biomimetic catalytic activity of their copper(II) complexes
期刊名称:Journal of Materials and Environmental Science
印刷版ISSN:2028-2508
出版年度:2016
卷号:7
期号:8
页码:3035-3042
出版社:University of Mohammed Premier Oujda
摘要:An efficient route of synthesis of symmetric and dissymmetric [1,2,3]Triazole-containing ligands via the easily accessible benzyl-protected alkylating synthon benzyl-4-bromomethyl-1H-1,2,3-triazole(1) is reported. The structure of L 2 was confirmed by X-ray diffraction. First studies of the catalytic activity of their copper(II) complexes suggest that these complexes could be proposed as catalyst for the oxidation of alcohols in carbonyl compounds or as artificial enzymes.