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  • 标题:A new route for the synthesis of symmetric and dissymmetric bis-triazol ligands and the catechol oxidase biomimetic catalytic activity of their copper(II) complexes
  • 作者:Allali M. ; Mouacha Y. ; Allali N.
  • 期刊名称:Journal of Materials and Environmental Science
  • 印刷版ISSN:2028-2508
  • 出版年度:2016
  • 卷号:7
  • 期号:8
  • 页码:3035-3042
  • 出版社:University of Mohammed Premier Oujda
  • 摘要:An efficient route of synthesis of symmetric and dissymmetric [1,2,3]Triazole-containing ligands via the easily accessible benzyl-protected alkylating synthon benzyl-4-bromomethyl-1H-1,2,3-triazole(1) is reported. The structure of L 2 was confirmed by X-ray diffraction. First studies of the catalytic activity of their copper(II) complexes suggest that these complexes could be proposed as catalyst for the oxidation of alcohols in carbonyl compounds or as artificial enzymes.
  • 关键词:Diaza;crown ether; N;N;diamine; [1;2;3]Triazole; catalytic activity.
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