With the growing concern with our environment, the practice degree of green supply chain management I attractgetting more and more attention from academic and industry. Therefore, studying green supply chain management practice is a very meaningful work. Green supply chain management performance appraisal will involve a lot of indicators, and there are usually have dependence and feedback relationship between the various indicators. Therefore, this paper introduces how to use the ANP method to solve the problem effectively. This paper uses the Super Decisions 1.6.0 software to calculate the final weight of the network layer indicators, and assesses the performance level of three enterprises which have different implementation degree in green supply chain. Green supply chain management performance evaluation index system and the network model are established by the network level, which provide an effective solution for green supply chain management performance appraisal. The empirical research results prove the method are scientific and feasible to solve the problem of green supply chain management performance appraisal.