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  • 标题:Synthesis of dl-aleprylic acid
  • 本地全文:下载
  • 作者:Akira Tanaka
  • 期刊名称:JLR Papers In Press
  • 印刷版ISSN:0022-2275
  • 电子版ISSN:1539-7262
  • 出版年度:1969
  • 卷号:10
  • 期号:6
  • 页码:681-682
  • 语种:English
  • 出版社:American Society for Biochemistry and Molecular Biology
  • 摘要:dl -Aleprylic acid [7-(cyclopent-2′-en-1′-yl)-heptanoic acid], a natural constituent of chaulmoogra oil with reputed antileprosy properties, has been synthesized. Electrolysis of a mixture of (cyclopent-2′-en-1′-yl)-acetic acid and methyl monoester of heptanedioic acid in methanol yielded, after saponification of the reaction products, the racemic mixture.
  • 关键词:Kolbe reaction ; cross coupling ; cyclopent-2-enyl fatty acid
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