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  • 标题:The structure of plasmalogens: VI. Configuration of the double bond in the α,β-unsaturated ether linkage of phosphatidal choline
  • 本地全文:下载
  • 作者:William T. Norton ; Eugene L. Gottfried ; Maurice M. Rapport
  • 期刊名称:JLR Papers In Press
  • 印刷版ISSN:0022-2275
  • 电子版ISSN:1539-7262
  • 出版年度:1962
  • 卷号:3
  • 期号:4
  • 页码:456-459
  • 语种:English
  • 出版社:American Society for Biochemistry and Molecular Biology
  • 摘要:The infrared spectrum of α-1-alkenyl glyceryl ether, prepared from pure phosphatidal choline, shows a singlet at 6.00 μ (1667 cm−1) and a band at 13.55 μ (738 cm−1). These two bands disappear after hydrogenation of the unsaturated ether. No appreciable absorption at 10–11 μ (1000-910 cm−1) was found. This evidence is consistent with the properties of cis - and not with those of trans -1-alkenyl alkyl ethers, and permits the assignment of the cis configuration to the double bond in the α,β-unsaturated ether linkage.
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