标题:Studies on the Syntheses of Hydrogenated Quinolines and Isoquinolines as Analgesics. XIV. Synthesis of 6-Hydroxy-4a, 10-trimethylene-1, 2, 3, 4, 4a, 9, 10, 10a-octahydrophenanthridine (Supplement).
摘要:Some considerations were made on the steric configuration of 3-hydroxy-9-aza-des-N-morphinan synthesized previously. It was thereby established that the octahydroquinoline formed during the course of its synthesis has a trans-configuration and that its cyclized product and demethylated, objective compound have the same steric configuration as that of morphine.