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  • 标题:Sulfur-containing Pyridine Derivatives. LI. 2, 6-Diamino-3-mercaptopyridine Derivatives
  • 本地全文:下载
  • 作者:Kan-ichi UEDA
  • 期刊名称:Chemical and Pharmaceutical Bulletin
  • 印刷版ISSN:0009-2363
  • 电子版ISSN:1347-5223
  • 出版年度:1956
  • 卷号:4
  • 期号:5
  • 页码:402-405
  • DOI:10.1248/cpb1953.4.402
  • 出版社:The Pharmaceutical Society of Japan
  • 摘要:1) In Part XXXVIII, it was reported that when 2, 6-diamino-3-methylthiopyridine (III) was refluxed with acetic anhydride, 2, 6-diacetamido-3-methylthiopyridine (VI) was produced. However, it was found that this acetate was a triacetate, the structure of which must be represented by either 2-acetamido-6-acetimido-N-acetyl-3-methylthiopyridine (Va) or 6-acetamido-2-acetimido-N-acetyl-3-methylthiopyridine (Vb), and the relationship between the diacetate (VI) and the triacetate (V) was investigated. 2) Oxidation products of (V) and (VI) were obtained.
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