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  • 标题:Sulfur-containing Pyridine Derivatives. XLV. Synthesis of 2-Mercapto-3-amino-6-chloropyridine Derivatives
  • 本地全文:下载
  • 作者:Torizo Takahashi ; Yoshifumi Maki
  • 期刊名称:Chemical and Pharmaceutical Bulletin
  • 印刷版ISSN:0009-2363
  • 电子版ISSN:1347-5223
  • 出版年度:1955
  • 卷号:3
  • 期号:5
  • 页码:361-364
  • DOI:10.1248/cpb1953.3.361
  • 出版社:The Pharmaceutical Society of Japan
  • 摘要:1) 2-Mercapto-3-amino-6-chloropyridine obtained by barium hydroxide hydrolysis of 6-chloro-2'-aminopyrido [2, 3 : 5', 4']thiazole afforded its thioethers (alkyl, Pyridyl) and their derivatives in good yield. 2) A phenomenon analogous to the Smile's rearrangement was recognized in 2-[5'-nitropyridyl-(2')]thio-3-amino-6-chloropyridine.
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