标题:Studies on the Syntheses of Isoquinoline Derivatives and their Analogs. XXXV. Migration of the Double Bond of Pyrimidinoisoquinolines and presumption of their Structures by the Infrared Absorption Spectra
摘要:In the preceding paper it was shown that two kinds of pyrimidinoisoquinoline of a higher and lower melting point were obtained by the cyclization of N-(p-nitrobenzoyl-β-alanyl)-β-3, 4-dimethoxyethylamine. Later, the structure of two were examined through the infrared spectra and some conclusions were drawn from them. A newer method for their mutual transformation method was found and successfully achieved by boiling the lower-melting substance with 10% hydrochloric acid. Furthermore, the same reaction was found to occur between compounds having no nitro group.