文章基本信息
- 标题：Studies in Stereochemistry. X. dl-Phenylserinols : A New Synthesis and its Stereochemical Findings. (3). Ring Opening of dl-threo-2-Phenyl-4-phenylhydroxymethyl-⊿2-oxazoline in Basic Media.
- 本地全文：下载
- 作者：Tanezo Taguchi ; Munemitsu Tomoeda
- 期刊名称：Chemical and Pharmaceutical Bulletin
- 印刷版ISSN：0009-2363
- 电子版ISSN：1347-5223
- 出版年度：1956
- 卷号：4
- 期号：6
- 页码：473-476
- DOI：10.1248/cpb1953.4.473
- 语种：English
- 出版社：The Pharmaceutical Society of Japan
- 摘要：
The treatment of dl-threo-1-phenyl-1-benzoyloxy-2-amino-3-bromopropane (I) hydrobromide in basic media yielded dl-1-phenyl-2-benzoylaminoprop-1-en-3-ol (or dl-1-phenyl-2-benzoyliminopropan-3-ol) (IV) via dl-threo-2-phenyl-4-phenylhydroxymethyl-⊿2-oxazoline (II). dl-threo-1-Phenyl-2-benzoylaminopropane-1, 3-diol (III) was also formed by treatment of hydrobromide of (I) with potassium acetate and hydrous ethanol. These formation mechanisms were discussed on the ground of stereochemical findings.
