首页    期刊浏览 2024年07月22日 星期一
登录注册

文章基本信息

  • 标题:Application of the Robinson Dehydrogenation Reaction. I. A Synthesis of 2, 3-Dimethoxy-6H-indolo[2, 1-a] isoindole
  • 本地全文:下载
  • 作者:Shigehiko Sugasawa ; Yuichi Kanaoka
  • 期刊名称:Chemical and Pharmaceutical Bulletin
  • 印刷版ISSN:0009-2363
  • 电子版ISSN:1347-5223
  • 出版年度:1955
  • 卷号:3
  • 期号:4
  • 页码:266-270
  • DOI:10.1248/cpb1953.3.266
  • 出版社:The Pharmaceutical Society of Japan
  • 摘要:For the purpose of examining the scope of the Robinson dehydrogenation reaction as a tool for building up polynuclear condensed nitrogen-ring compounds, in which the nitrogen atom is common to two rings, 1-(3', 4'-dihydroxybenzyl) isoindoline and its N-methyl derivative were treated with chloranil in ethanolic solution. The former gave the expected 2, 3-dihydroxy-6H-indolo[2, 1-a] isoindole, characterized as its dimethyl derivative, but the latter failed to give any definite oxidation product under a variety of working conditions, yielding only intractable, dark blue tarry substance.
国家哲学社会科学文献中心版权所有