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  • 标题:Metabolic Products of Fungi. VI. The Structure of Skyrin. (2). Synthesis of Skyrin β, β'-Dimethyl Ether
  • 本地全文:下载
  • 作者:Osamu Tanaka ; Chikara Kaneko
  • 期刊名称:Chemical and Pharmaceutical Bulletin
  • 印刷版ISSN:0009-2363
  • 电子版ISSN:1347-5223
  • 出版年度:1955
  • 卷号:3
  • 期号:4
  • 页码:284-286
  • DOI:10.1248/cpb1953.3.284
  • 出版社:The Pharmaceutical Society of Japan
  • 摘要:Skyrin β, β'-dimethyl ether was synthesized by the Ullmann condensation of 8-bromoemodin trimethyl ether followed by a partial demethylation. The structure of skyrin, therefore, was unequivocally established as 2, 4, 5, 2', 4', 5'-hexahydroxy-7, 7'-dimethyl-bianthraquinone-(1, 1').
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