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  • 标题:フタル酸エステル類の熱分解に関する研究(第5報)ジ-n-ブチルフタレートの熱分解と反応生成物の分析
  • 本地全文:下载
  • 作者:道祖土 勝彦 ; 渡部 武則 ; 本橋 重康
  • 期刊名称:Journal of Health Science
  • 印刷版ISSN:1344-9702
  • 电子版ISSN:1347-5207
  • 出版年度:1981
  • 卷号:27
  • 期号:1
  • 页码:16-22
  • DOI:10.1248/jhs1956.27.16
  • 出版社:The Pharmaceutical Society of Japan
  • 摘要:As a study of the thermal behavior of phthalic acid esters (PAE's), the thermal decomposition of di-n-butylphthalate (DBP) was carried out in a flow system at 250-500°. The major products were butene-1, butanol and phthalic anhydride (PA). Benzoic acid, butyl benzoate, phthalic acid and monobutyl phthalate (monoester), as minor products, were also isolated and identified. These minor products, especially phthalic acid and monoester, were so unstable to the heat treatment that they were not isolated in a conventional GC analysis. A simple one step analysis was achieved by the use of a GC, by pretreating the products with diazomethane to improve their heatstability. This analytical method made clear the composition of commercial polyvinyl chloride sheet (PVC) for agricultural use. It was found that the plasticizer it originally contained, di (2-ethylhexyl) phthalate (DEHP), were partially decomposed and identified the decomposition products. 2-Ethylhexanol, PA and mono 2-ethylhexyl phthalate, the thermal decomposition products of DEHP, were analyzed to be 0.1%, 0.7% and 0.1% of the products, respectively.
  • 关键词:phthalic acid esters;di-n-butyl phthaiate;mono butyl phthalate;phthalic anhydride;bis (2-ethylhexyl) phthalate;polyvinyl chloride;environmental pollution;thermal decomposition;analysis of phthalate
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