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  • 标题:Studies on Anthelmintics. XXXII. The Absolute Configuration of Santonin Isomers. (1). Naturally Occurring Santonins
  • 本地全文:下载
  • 作者:Masao Sumi
  • 期刊名称:Chemical and Pharmaceutical Bulletin
  • 印刷版ISSN:0009-2363
  • 电子版ISSN:1347-5223
  • 出版年度:1956
  • 卷号:4
  • 期号:3
  • 页码:158-162
  • DOI:10.1248/cpb1953.4.158
  • 出版社:The Pharmaceutical Society of Japan
  • 摘要:(-)-α-Santonin has been correlated stereochemically with (+)-11-carboxy-3-oxoeusanton-4-enic acid (X) and by the investigation of molecular rotation of the latter the absolute configuration of the former has been deduced. It has been shown that(-)-α-santonin belongs to the same stereochemical type as steroids.(-)-β-Santonin proved to be the C11-epimer of (-)-α-santonin.
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