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  • 标题:Studies in Stereochemistry. IX. dl-Phenylserinols : A New Synthesis and its Stereochemical Findings.(2)
  • 本地全文:下载
  • 作者:Tanezo Taguchi ; Munemitsu Tomoeda ; Haruki Fukuyama
  • 期刊名称:Chemical and Pharmaceutical Bulletin
  • 印刷版ISSN:0009-2363
  • 电子版ISSN:1347-5223
  • 出版年度:1956
  • 卷号:4
  • 期号:2
  • 页码:80-84
  • DOI:10.1248/cpb1953.4.80
  • 出版社:The Pharmaceutical Society of Japan
  • 摘要:In the derivation of dl-1-phenyl-2-acylamino-1, 3-dibromopropanes to dl-phenyl-serinols, the stepwise displacement of bromine atoms by hydroxyl groups was examined in connection with earlier conclusions. It was found that the proximity of acyl group to the displacement centre favored the internal Sn2 and that its distance from the neighborhood favored Sn1 in the solvolytic condition.
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