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  • 标题:Saponins of Japnaese Dioscoreaceae. VI. The Structure of Gracillin.(1)
  • 本地全文:下载
  • 作者:Takeo Tsukamoto ; Toshio Kawasaki
  • 期刊名称:Chemical and Pharmaceutical Bulletin
  • 印刷版ISSN:0009-2363
  • 电子版ISSN:1347-5223
  • 出版年度:1956
  • 卷号:4
  • 期号:2
  • 页码:104-108
  • DOI:10.1248/cpb1953.4.104
  • 出版社:The Pharmaceutical Society of Japan
  • 摘要:Gracillin, a new diosgenin glycoside which was present together with dioscin in the water-insoluble saponins obtained from the rhizome of Dioscorea gracillima Miq., was proved to be composed of one mole each of diosgenin and of L-rhamnose and two of D-glucose. It afforded two prosapogenins C and A on partial hydrolysis, both of which were isolated and proved to be trillin (diosgenin monoglucoside) and glucosidoglucoside, respectively. Two possible formulae (I) and (II) were proposed for gracillin.
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