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  • 标题:Sulfur-containing Pyridine Derivatives. XLIII.1)Synthesis of Pyrido[2, 3 : 2', 3']-p-thiazines. (2)
  • 本地全文:下载
  • 作者:Torizo Takahashi ; Yoshifumi Maki
  • 期刊名称:Chemical and Pharmaceutical Bulletin
  • 印刷版ISSN:0009-2363
  • 电子版ISSN:1347-5223
  • 出版年度:1955
  • 卷号:3
  • 期号:2
  • 页码:92-96
  • DOI:10.1248/cpb1953.3.92
  • 出版社:The Pharmaceutical Society of Japan
  • 摘要:1) Synthesis of derivatives of 6-chloropyrido[2, 3 : 2', 3']-p-thiazine, 5'-oxo-5', 6'-dihydropyrido[2, 3 : 2', 3']-p-thiazine, pyrido[3, 4 : 3', 2']-p-thiazine, and 2-azaphenothiazine was described. 2) Some of their chemical properties, especially their behavior to acids and alkalis, were investigated. 3) The reaction using 2-mercapto-3-amino-6-chloropyridine as one of the starting materials often afforded the by-product of orange rhombics, m.p.210°, which was proved to be 3, 3'-diamino-6, 6'-dichlorodipyridyl 2, 2'-disulfide.
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