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  • 标题:Chlorination of Monochlorodimedone with Chloramines I. Kinetics of the Chlorination
  • 本地全文:下载
  • 作者:MARIKO TACHIKAWA ; MASAKATSU TEZUKA ; RYOJI SAWAMURA
  • 期刊名称:Journal of Health Science
  • 印刷版ISSN:1344-9702
  • 电子版ISSN:1347-5207
  • 出版年度:1993
  • 卷号:39
  • 期号:3
  • 页码:202-206
  • DOI:10.1248/jhs1956.39.3_202
  • 出版社:The Pharmaceutical Society of Japan
  • 摘要:The kinetics of monochlorodimedone (MCD) chlorination with sodium hypochlorite (NaOCl), chloroisocyanurates (2Cl-and 3Cl-ICA), N-chlorosuccinimide (Cl-succinimide), and chloramine T and B were studied. The chlorination of MCD was recognized by a decrease in absorbance at 290 nm and at pH 7. Instantaneous chlorinations occurred with NaOCl and chloroisocyanurates. The rate constants for the chlorination with Cl-succinimide and chloramine T and B were determined. The reactions were determined to be second order-first order in each reactant, and were dependent on temperature. The observed second order rate constants at 15°C for Cl-succinimide, and at 25°C for chloramine T and B were 1500, 61.8 and 41.5 M-1·S-1, respectively.
  • 关键词:monochlorodimedone;chlorination kinetics;chloramines;rate constant
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