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  • 标题:Polyvinylpolypyrrolidone Supported Brønsted Acidic Catalyst for Esterification
  • 本地全文:下载
  • 作者:Song Wang ; Chengcheng Tian
  • 期刊名称:International Journal of Polymer Science
  • 印刷版ISSN:1687-9422
  • 电子版ISSN:1687-9430
  • 出版年度:2016
  • 卷号:2016
  • DOI:10.1155/2016/8104838
  • 出版社:Hindawi Publishing Corporation
  • 摘要:A polyvinylpolypyrrolidone (PVPP) supported Brønsted acidic catalyst (PVPP-BSHSO4) was prepared by coupling SO3H-functionalized polyvinylpolypyrrolidone with H2SO4 in this work. After the characterization through FT-IR, FESEM, TG, BET, and elemental analysis, it was found that 1,4-butane sultone (BS) and sulfuric acid reacted with PVPP and were immobilized on PVPP surface. The prepared PVPP-BSHSO4 catalyst shows high catalytic activity for a series of esterification reactions and could be separated from the reacted mixture easily. Moreover, this catalyst could be recycled and reused for six times without significant loss of catalytic performance.
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