期刊名称：Proceedings of the National Academy of Sciences
印刷版ISSN：0027-8424
电子版ISSN：1091-6490
出版年度：2002
卷号：99
期号：18
页码：11579-11582
DOI：10.1073/pnas.182297599
语种：English
出版社：The National Academy of Sciences of the United States of America
摘要：The H3O- anion has stable and metastable structures that resemble configurations in the vicinity of the transition state for the neutral reactions OH + H2 {leftrightarrow} H2O + H. Photoelectron spectroscopy of this anion probes the neutral reaction dynamics in the critical transition-state region. Accurate quantum dynamics calculations of the photoelectron intensity and photodissociation product energies are shown to provide a quantitatively reliable means of interpreting such experimental observations and reveal a detailed picture of the reaction dynamics.
