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  • 标题:Electronic properties of some protein--methylglyoxal complexes
  • 本地全文:下载
  • 作者:S Bone ; T J Lewis ; R Pethig
  • 期刊名称:Proceedings of the National Academy of Sciences
  • 印刷版ISSN:0027-8424
  • 电子版ISSN:1091-6490
  • 出版年度:1978
  • 卷号:75
  • 期号:1
  • 页码:315-318
  • DOI:10.1073/pnas.75.1.315
  • 语种:English
  • 出版社:The National Academy of Sciences of the United States of America
  • 摘要:Steady-state conductivity measurements and dielectric measurements in the frequency range 10(-5) to 100 Hz are reported for samples of bovine serum albumin, casein, and lysozyme complexed with methylglyoxal. Compared with the untreated proteins, the brown complexed proteins exhibit an increased conductivity and free electron spin density, together with a low-frequency dielectric dispersion. These results can be taken as evidence that the interaction with methylglyoxal results in the proteins possessing an increased electronic activity associated with the creation of mobile electron holes within the valence band states of the protein molecules.
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