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  • 标题:A suggestion for naming faces of ring compounds
  • 本地全文:下载
  • 作者:Irwin A. Rose ; Kenneth R. Hanson ; Keith D. Wilkinson
  • 期刊名称:Proceedings of the National Academy of Sciences
  • 印刷版ISSN:0027-8424
  • 电子版ISSN:1091-6490
  • 出版年度:1980
  • 卷号:77
  • 期号:5
  • 页码:2439-2441
  • DOI:10.1073/pnas.77.5.2439
  • 语种:English
  • 出版社:The National Academy of Sciences of the United States of America
  • 摘要:Discussion of the topology of interaction of ring compounds with macromolecules and receptors requires a system for naming the faces of the cyclic compound. An /{beta}-face nomenclature is suggested that is based on the clockwise/counterclockwise direction of ascending numbering in the ring with the lowest numbered unshared ring atom. This system is applicable to a very broad range of compounds: sugars, cyclic bases, steroids, cyclitols, porphyrins, etc., and molecules with a single ring, fused rings, encompassing rings, and rings formed by head-to-tail polymerization.
  • 关键词:stereochemistry ; ring faces ; receptor sites
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