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  • 标题:Direct assignment of vitamin K1 as the secondary acceptor A1 in photosystem I.
  • 本地全文:下载
  • 作者:S W Snyder ; R R Rustandi ; J Biggins
  • 期刊名称:Proceedings of the National Academy of Sciences
  • 印刷版ISSN:0027-8424
  • 电子版ISSN:1091-6490
  • 出版年度:1991
  • 卷号:88
  • 期号:21
  • 页码:9895-9896
  • DOI:10.1073/pnas.88.21.9895
  • 语种:English
  • 出版社:The National Academy of Sciences of the United States of America
  • 摘要:The characteristic electron spin polarized electron paramagnetic resonance (ESP EPR) signal observed in photosystem I (PSI) has been previously assigned to a radical pair composed of the oxidized primary donor and a reduced vitamin K1. Under conditions in which Bottin, H. & Setif, P. [(1991), Biochim. Biophys. Acta 105, 331-336] proposed that A1 is doubly reduced, the ESP EPR signal was not observed. Therefore, the ESP EPR signal can be directly attributed to A-1, and vitamin K1 can be assigned as this PSI acceptor. The ESP EPR signal was partially restored by removal of the chemical reductants.
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