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  • 标题:Study of an Energetic-oxidant Co-crystal: Preparation, Characterisation, and Crystallisation Mechanism
  • 本地全文:下载
  • 作者:Han Gao ; Wei Jiang ; Jie Liu
  • 期刊名称:Defence Science Journal
  • 印刷版ISSN:0976-464X
  • 出版年度:2017
  • 卷号:67
  • 期号:5
  • 页码:510-517
  • 语种:English
  • 出版社:Defence Scientific Information & Documentation Centre
  • 其他摘要:An energetic co-crystal consisting of the most promising military explosive 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) and the most well-known oxidant applied in propellants ammonium perchlorate has been prepared with a simple solvent evaporation method. Scanning electron microscopy revealed that the morphology of co-crystal differs greatly from each component. The X-ray diffraction spectrum, FTIR, Raman spectra, and differential scanning calorimetry characterisation further prove the formation of the co-crystal. The result of determination of hygroscopic rate indicated the hygroscopicity was effectively reduced. At last, the crystallisation mechanism has been discussed.
  • 关键词:Energetic co-crystal;Ammonium perchlorate;CL-20, Solvent evaporation method;Intermolecular hydrogen bond
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