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  • 标题:Solvent- and Catalyst-Free Microwave-Assisted Decarboxylation of Malonic Acid Derivatives
  • 本地全文:下载
  • 作者:Fanny Araceli Cabrera-Rivera ; Luis Gabriel Hernández-Vázquez ; Patricia Flores-Sánchez
  • 期刊名称:Green and Sustainable Chemistry
  • 印刷版ISSN:2160-6951
  • 电子版ISSN:2160-696X
  • 出版年度:2017
  • 卷号:07
  • 期号:04
  • 页码:270-280
  • DOI:10.4236/gsc.2017.74021
  • 语种:English
  • 出版社:Scientific Research Publishing
  • 摘要:It has been found that microwave assisted decarboxylation of malonic acid derivatives can be achieved under solvent-free and catalyst free conditions. This new method produces the corresponding carboxylic acid in a pure manner and with a high yield in a very short reaction time: 3 - 10 min. In general terms, the condition under which this reaction is carried out accelerates the decarboxylation significantly of a series of disubstituted malonic acid derivatives, and makes this new process efficient, easy and environmentally friendly.
  • 关键词:Microwave;Decarboxylation;Malonic Acid Derivatives;Solvent-Free;Catalyst-Free;Green Chemistry
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