文章基本信息
- 标题：Microwave-Assisted Debromination of α-Bromoketones with Triarylstibanes in Water
- 本地全文：下载
- 作者：Yuki Murata ; Yoshiyuki Sugawara ; Mio Matsumura 等
- 期刊名称：Chemical and Pharmaceutical Bulletin
- 印刷版ISSN：0009-2363
- 电子版ISSN：1347-5223
- 出版年度：2017
- 卷号：65
- 期号：11
- 页码：1081-1084
- DOI：10.1248/cpb.c17-00533
- 语种：English
- 出版社：The Pharmaceutical Society of Japan
- 摘要：
Several α-bromoarylketones were reacted with triarylstibanes under microwave irradiation in water to obtain the corresponding debrominated ketones. Under similar reaction conditions, 1,2-elimination of vic -dibromides in water afforded the corresponding E -olefins. This reaction is the first example of organoantimony compounds utilized for organic transformation in water.
- 关键词：microwave;debromination;α-bromoketone;triarylstibane;water
