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  • 标题:Versatile Amine-Promoted Mild Methanolysis of 3,5-Dinitrobenzoates and Its Application to the Synthesis of Colorado Potato Beetle Pheromone
  • 本地全文:下载
  • 作者:Yumiko Yamano ; Haruna Sasaki ; Akimori Wada
  • 期刊名称:Chemical and Pharmaceutical Bulletin
  • 印刷版ISSN:0009-2363
  • 电子版ISSN:1347-5223
  • 出版年度:2017
  • 卷号:65
  • 期号:10
  • 页码:940-944
  • DOI:10.1248/cpb.c17-00462
  • 语种:English
  • 出版社:The Pharmaceutical Society of Japan
  • 摘要:

    A mild deacylation method for 3,5-dinitrobenzoates using methanolic solutions of amines, such as dialkylamines, was developed. The method’s versatility was confirmed by applying it to synthesizing a key intermediate for Colorado potato beetle pheromone.

  • 关键词:3,5-dinitrobenzoate;amine-promoted methanolysis;selective deacylation;Colorado potato beetle pheromone
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