A fermented beverage of plant extracts (Super Ohtaka^®) was prepared from about 50 kinds of fruits and vegetables. This natural fermentation was performed by yeast ( Zygosaccharomyces spp. and Pichia spp.) and lactic acid bacteria ( Leuconostoc spp.) and resulted in the production of a novel fructopyranose-containing saccharide, which was subsequently isolated using carbon-Celite column chromatography and preparative-HPLC. The structure of the saccharide was determined using MALDI-TOF MS and NMR, and the saccharide was identified as β-D-fructopyranosyl-(2→6)-β-D-fructofuranosyl-(2↔1)-α-D-glucopyranoside. This is the first description of this novel saccharide and its isolation from a natural source.