期刊名称：IOP Conference Series: Earth and Environmental Science
印刷版ISSN：1755-1307
电子版ISSN：1755-1315
出版年度：2018
卷号：170
期号：2
页码：022036
DOI：10.1088/1755-1315/170/2/022036
语种：English
出版社：IOP Publishing
摘要：The molybdenum dialkyldithiophosphate (MoDTP) with the feature of self-sulfurization, has been prepared, characterized and evaluated in the slurry-phase hydrocracking of Karamay atmospheric residue (KAR) as catalyst precursor. The self-sulfurization of MoDTP achieved fine MoS2 particles with lower crystallinity and higher surface Mo4+ proportion in contrast to that of molybdenum naphthenate, implying the well sulfurized statement of MoDTP. Low coke yield and large asphaltene aggregate size using MoDTP proved the favorable hydrogenation activity of self-sulfurized catalyst in hydrocracking of residue.
