期刊名称:Proceedings of the National Academy of Sciences
印刷版ISSN:0027-8424
电子版ISSN:1091-6490
出版年度:2018
卷号:115
期号:39
页码:E9058-E9066
DOI:10.1073/pnas.1810102115
语种:English
出版社:The National Academy of Sciences of the United States of America
摘要:Intense pulsed-laser fields have provided means to both induce spatial alignment of molecules and enhance strength of chemical bonds. The duration of the laser field typically ranges from hundreds of picoseconds to a few femtoseconds. Accordingly, the induced “laser-dressed” properties can be adiabatic, existing only during the pulse, or nonadiabatic, persisting into the subsequent field-free domain. We exemplify these aspects by treating the helium dimer, in its ground